945394 MATERIAL SAFETY DATA SHEET: USA
MEDICAL EMERGENCIES ONLY (24 Hour Service): 1-800-328-0026
Medical Calls from Outside of the USA: 1-651-222-5352
Ecolab Vehicle Care Division
Ecolab Center St. Paul MN 55102
Product Information: 1-877-ECOWASH Issue Date: August 28, 2002
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1.0 IDENTIFICATION /
1.1 Product Name: 690 PRESOAK I
1.2 Product Type: Hydrofluoric Presoak Detergent
1.3 Hazard Rating: Health: 3 Fire: 1 Reactivity: 0
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Substances Subject to SARA 313 Reporting Are Indicated by "#"
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2.0 HAZARDOUS COMPONENTS / (in mg/m3)
CAS No. % PEL TWA
2.1 # Hydrofluoric acid (HF) 7664-39-3 8 3ppm No*
*ACGIH STEL = 3ppm C
2.2 Ammonium bifluoride 1341-49-7 2 2.5* 2.5*
*As Fluoride
2.3 Linear alkyl aryl sulfonic acid 27176-87-0 21 No No
2.4 # 2-Butoxyethanol 111-76-2 8 240 97
(ethylene glycol monobutyl ether) (absorbed through skin)
2.5 Stoddard solvent 8052-41-3 5-20 2900 525*
*NIOSH STEL (15 min) = 1800 C
2.6 Nonionic and Anionic surfactants mixture 5-20 No No
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STEL = ACGIH short term exp. limit (15 min) PEL = OSHA 8 hr ave in air
TWA = ACGIH 8 hr average C = ceiling limit in air, do not exceed
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3.0 PHYSICAL DATA /
3.1 Appearance: Clear straw-colored liquid; citrus fragrance
3.2 Solubility in Water: Mixes with water in all proportions
3.3 pH: 2.0 - 3.0 (at 1%)
3.4 Initial Boiling Point: 212 deg F / 100 deg C
3.5 Specific Gravity: 1.024 @ 80 deg F / 27 deg C
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4.0 FIRE AND EXPLOSION DATA /
4.1 Special Fire Hazards: High heat will cause acidic vapors. May flash.
4.2 Fire Fighting Methods: Use method appropriate for surrounding fire.
4.3 Flash Point: estimated 150 deg F / 66 deg C
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5.0 REACTIVITY DATA /
5.1 Stability: Stable under normal conditions of use and handling.
5.2 Conditions to Avoid: Mix only with water. Reacts with metals;
reacts vigorously with alkaline chemicals.
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6.0 SPILL OR LEAK PROCEDURES / USE PROPER PROTECTIVE EQUIPMENT
6.1 Cleanup: Dike or dam large spills. Pump to containers or soak up
on inert absorbent. Flush residue to sanitary sewer.
6.2 Waste Disposal: Consult state/local authorities for limits on
chemical waste disposal. Unused product is RCRA Corrosive (D002).
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7.0 HEALTH HAZARD DATA / DANGER - Contains Hydrogen Fluoride
7.1 Effects of Overexposure to Concentrate:
Eyes: CAUSES SEVERE CHEMICAL BURNS. May cause blindness.
Skin: CAUSES SEVERE CHEMICAL BURNS.
If Swallowed: HARMFUL OR FATAL. Causes chemical burns of mouth,
throat and stomach.
If Inhaled: Vapors or mist cause irritation, including a burning tast
7.2 Chronic low level exposure may result in mottling of teeth, joint stif
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8.0 FIRST AID /
8.1 Eyes: Flush at once with cool running water. Remove contact lenses.
Continue flushing for 30 minutes, holding eyelids apart so as to
rinse entire eye. SEEK MEDICAL ATTENTION IMMEDIATELY.
8.2 Skin: Immediately flush skin with plenty of cool running water while
and flush for 15 minutes. Apply calcium gluconate gel, if available,
8.3 If Swallowed: Immediately rinse mouth; then drink 2 glasses of milk,
if available, or water. If available, take several calcium antacid
tablets (eg TUMS) or several tablespoons of milk of magnesia. DO NOT
induce vomiting. NEVER give anything by mouth to an unconscious
person. SEEK MEDICAL ATTENTION IMMEDIATELY.
8.4 If Inhaled: Immediately move to fresh air.
GET IMMEDIATE MEDICAL ATTENTION TO TREAT ANY CONTACT WITH HYDROGEN FLUORIDE
1-800-328-0026, A POISON CONTROL CENTER, OR A PHYSICIAN
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9.0 PROTECTIVE MEASURES /
9.1 FOR CONCENTRATE:
Eyes: Use chemical splash goggles. For continued or severe
exposure wear a face shield over the goggles.
Skin: Use impervious glove, other protection to avoid skin contact.
Respiratory: Avoid breathing mists or vapors containing this product.
Ventilate to maintain air levels below exposure limits.
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10.0 ADDITIONAL INFORMATION /
10.1 DOT: CORROSIVE LIQUID, TOXIC, N.O.S. (HYDROFLUORIC ACID, AMMONIUM
HYDROGEN DIFLUORIDE),8(6.1), UN2922, II
10.2 Purpose of 8/28/2002 issue: Formula change, associated edits; add
line 10.1. Replaces July 30, 1999 issue.
KEEP OUT OF REACH OF CHILDREN
NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR
CONTINUING ACCURACY OF THIS INFORMATION.
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